Fundamentally; air, oxygen and nitrogen will all behave exactly the same in terms of pressure change for each 10 degrees of temperature change. However temperature alone is not the whole story.
Ambient air contains moisture, nitrogen does not. If moisture is present it contributes to a greater change in pressure simply because at lower temperatures water condenses to become a liquid. The liquid form of water occupies very little volume and contributes only a negligible pressure to the tire. But at higher temperatures, such as those in a running tire, water evaporates inside the tire and becomes a gas which increases pressure in the tire.
Ambient air contains about 21% oxygen. Oxygen’s smaller molecular size allows it to permeate through the rubber of the tire. By inflating with nitrogen, which is much less permeable than oxygen, the pressure changes due to oxygen loss are greatly reduced.
The racing industry is correct; nitrogen is more predictable. Because nitrogen is dry it has no moisture to contribute extra pressure changes with temperature. Because nitrogen permeates out much slower than oxygen pressure changes due to that leakage are almost eliminated compared with ambient air.
Let’s get a little deeper into the science. Keep in mind that the air in your tires changes about 1psi for every 10 degree temperature change. This means that a significant change in temperature will create a significant change in your tire pressure. Here is a set of Ideal Gas Law calculations showing the effects of a 10F degree temperature change on truck and passenger tires. The two sets of data represent different initial temperatures of 60F and 90F. This demonstrates that the magnitude of the pressure fluctuation differs depending on initial conditions but only slightly.
(Taken from the get nitrogen website)
